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Precision Thin-Film Deposition Platform

Precision Thin-Film
Deposition Platform

Primary application: Nanosolar Tile — transparent perovskite solar film for building-integrated photovoltaics

<$5k
Platform hardware cost vs.
$20k–$150k commercial systems
Sub-mm
Deposition accuracy across
full tool exchange cycles
Scalable
Multi-tool, multi-channel architecture —
channel count expands with application
01 — The Platform

A Purpose-Built Deposition System

The Rister platform is a precision multi-channel liquid handling and deposition system engineered for multi-material thin-film fabrication on flexible substrates. Developed in-house at HTS Resources, it delivers capabilities comparable to commercial dispensing systems costing $20,000–$150,000 — at a fraction of the price, and purpose-built for the specific demands of flexible substrate work in controlled atmospheres.

Built for where commercial systems fall short.

Existing commercial dispensing platforms are designed for rigid substrates, single-material workflows, and controlled manufacturing environments. The Rister platform was designed from the ground up for multi-material, multi-layer deposition on flexible film substrates — the configuration required for next-generation thin-film devices.

What Makes It Different

  • Purpose-engineered for flexible substrate deposition — not adapted from a rigid-substrate platform
  • Scalable multi-channel architecture — each tool head supports multiple independent dispensing channels (up to 8 demonstrated per tool), with multiple tools loadable per run. Total channel count expands with the application
  • Multi-material in a single run — dedicated tool heads per ink chemistry enable sequential or parallel deposition without substrate removal, making larger tile sizes and faster throughput practical
  • Near-zero cost to scale — syringe pumps, valves, and tool bodies are fabricated in-house on the same platform. Adding channels means printing more hardware, not purchasing expensive proprietary components
  • Heated dispensing at 60°C with PTFE-lined fluid paths — compatible with high-viscosity and temperature-sensitive inks
  • Integrated camera inspection with fiducial-based referencing — sub-millimeter accuracy maintained across tool exchanges
  • Designed for N₂ and controlled atmosphere environments — required for air-sensitive material systems
  • Compact and portable — the complete system can be transported and operated at external facilities
02 — Capabilities

Platform Capabilities

The platform's core capabilities address a broad range of thin-film deposition applications requiring precise, multi-material, multi-layer workflows on flexible substrates.

Scalable Multi-Channel Dispensing
Each tool head supports multiple independent channels (up to 8 demonstrated). Multiple tools per run multiply total channel count further. Sub-nanoliter to microliter volume range, tunable via flow rate, gantry speed, and nozzle gauge (10G–34G).
Mid-Run Tool Exchange
Dedicated tool heads per ink type enable faster throughput and larger substrate coverage compared to tip-swap workflows. Pipette load/unload supported for prototyping. Coordinate integrity maintained via camera referencing.
Camera-Based Inspection
Low-cost embedded camera with autofocus for real-time QC, fiducial referencing, and positional verification. Tool-offset measurement and correction.
Interdigitated Patterning
Line-array deposition with 150 µm minimum feature size. Configurable geometry via Printer Designer software — no G-code editing required.
Heatable Fluid System
60°C operating temperature with pressure compensation reservoir, stepper-driven syringe pumps, and automated IPA cleaning loop.
Controlled Atmosphere Ready
Designed for N₂ glovebox and controlled atmosphere operation — compatible with air-sensitive material systems including perovskite precursors.

Adjacent Application Areas

While perovskite BIPV is the current focus, the platform's capabilities apply directly to other thin-film deposition workflows:

Perovskite Solar — Active Flexible Biosensors Battery Electrode Printing Organic Electronics Combinatorial Materials R&D Microfluidic Fabrication
03 — Hardware

Toolchanger Platform

The Rister toolchanger is a purpose-built motion control and dispensing platform running proven open-motion-control firmware. Each tool head is a self-contained dispensing unit with printed syringe pumps and servo-actuated valves — all fabricated in-house. Tool heads support multiple channels (up to 8 demonstrated), and multiple tools can be loaded per run. All mechanical and fluid components are documented in the hardware repository.

Toolchanger 3D Model Viewer
Interactive WebGL viewer — explore the full assembly
Toolchanger 3D model viewer Open Viewer ↗

Specialized Tool Heads

01

Liquid Handling Tool

Multi-channel heated pipette tool at 60°C. PTFE tubing (1.5mm ID), removable polypropylene tips, 150 µm nozzles. Syringe pumps and servo-controlled valves are printed in-house — channels scale by printing additional hardware. Pipette load/unload supported for prototyping; dedicated tool heads used for production throughput.

02

UV Curing Tool

In-situ UV curing for layer stabilization and encapsulant crosslinking at ambient pressure.

03

Camera Inspection Tool

Raspberry Pi 5 with autofocus camera. Real-time QC, fiducial-based absolute referencing, sub-millimeter positional verification across tool swaps.

Purpose-Built Motion Control Fully Documented Architecture Scalable Multi-Channel Tools Up to 8ch Per Tool Demonstrated 150 µm Nozzles RPi 5 Camera Inspection

Video Demonstrations — Tool Loading & Pipette Handling

① Load Liquid Handling Tool
② Unload Liquid Handling Tool
③ Load Pipette Dispenser (25G example)
④ Eject Pipette Dispensers
04 — Fluid Management

Pressure Control System

Stable, repeatable pressure at the pipette tip is the core challenge in precision ink deposition. The system uses multi-stage pressure management to prevent dripping, air entrainment, and meniscus instability across the full deposition cycle.

  • Pressure compensation reservoir — liquid level sensor triggers automatic peristaltic refill
  • Stepper-driven syringe pump with servo-controlled 3-way valve: Input / Output / Pipette / Bypass positions
  • Sub-nanoliter accuracy — 1–10 µL aspiration at 1 µL/s; multiple cycles enable sub-nL delivery
  • Automated cleaning loop — IPA flush, exterior wash, and waste evacuation in a closed-loop process
  • Dynamic nozzle swapping — 10G–34G (0.26–2.69 mm) for control over line width and flow across different ink viscosities

Fluid Management System Diagrams

Fluid management figure 1

Figure 1 — Single syringe pump: pressure compensation reservoir, 3-way valve positions, and automated cleaning.

Fluid management figure 2

Figure 2 — Multichannel configuration (4 syringes) with valves, gantry frame, peristaltic pumps, and waste/wash stations.

05 — Software & Control

Control Architecture

Two purpose-built web applications replace static G-code macros with a visual, integrated control environment for the full fabrication workflow.

Printer Designer

Printer Designer
Bed layout · tip management · G-code builder · line array designer
Project Manager 3D Object Viewer Dispenser Manager G-code Builder Line Designer Open App ↗

Array Management System

Array Management System
Sample tracking · recipe library · real-time dispensing status
React + Vite + TypeScript Express + Socket.IO MongoDB Docker Compose
MethodEndpointDescription
GET/api/samplesList all samples
POST/api/samplesCreate a new sample
GET/api/samples/:idGet sample details
PATCH/api/samples/:id/statusUpdate sample status
POST/api/arrays/createCreate array grid
Open App ↗
06 — Primary Application

Nanosolar Tile

Nanosolar Tile is the platform's primary development application — a thin, flexible transparent perovskite solar film that turns existing windows and building facades into distributed power generation surfaces.

Nanosolar Tile transparent film

Transparent window-attached perovskite solar film — visible light passes through while sunlight is converted to electricity.

8–12%
Sunlight converted
to electricity
55–65%
Visible light
passes through
≤100°C
Process temperature —
no cleanroom required
<$15/m²
Target manufacturing
cost at scale

Visually indistinguishable from lightly tinted architectural glass. Retrofit-compatible — applies to existing windows without structural modification.

PV fabrication process flow

Top-down PV fabrication process flow — substrate preparation through encapsulation on flexible ITO-PET.

Why Perovskite on This Platform

  • Line-array architecture — interdigitated patterning achieves both high transparency and usable photovoltaic output simultaneously
  • Ambient-pressure processing — full stack deposited at ≤100°C, eliminating vacuum deposition requirements
  • Multi-material in sequence — hole transport, absorber, and electron transport layers deposited in a single substrate-loaded run
07 — Market Opportunity

The BIPV Opportunity

California's commercial buildings consume over 40% of the state's electricity. Current transparent solar film options are either too expensive to manufacture or require cleanroom infrastructure inaccessible to small developers — creating a gap that the Nanosolar Tile addresses directly.

"Every window a power generation surface."

Low-cost printable perovskite film changes the economics of building-integrated solar — making distributed generation viable on existing commercial glazing at under $15/m².

  • Reduces peak demand by generating power at the point of consumption
  • Lowers transmission losses through distributed generation on existing building envelopes
  • Enables daylighting credits while generating clean energy on-site
  • Retrofit-compatible — no structural modification required
08 — Process Validation

Validated Milestones

Platform status: Hardware, fluid management, and control software fully validated with mimic inks. Advancing to real-material ITO-PET deposition trials.
  • Aspiration and dispensing of mimic inks validated with 25G pipettes — tunable line width, volume, and flow rate confirmed
  • Multi-material toolchanger validated: full load/unload cycles mid-fabrication without coordinate loss
  • 3-drop precision array confirmed sub-millimeter placement accuracy through complete tool exchange workflow
  • Camera fiducial referencing and tool-offset measurement implemented and tested
  • Printer Designer integrated end-to-end: layout → dispenser config → G-code → execution

Mimic Ink Validation Approach

All hardware and process development uses rheology-matched proxy inks before transitioning to actual perovskite precursors. Mimic inks (water + xanthan gum at varying concentrations) match the flow characteristics of perovskite precursor inks and can be dispensed with 34G needles at room temperature — enabling full process validation without hazardous material handling.

Mimic Ink Recipes

Proxy ink formulations matched to target perovskite ink viscosities for hardware and process validation.

Precision Assessment: 3-drop array with reference markers

3-drop precision array

Three drops placed within pen-marked target zones after full camera toolchange + liquid handler reload + pipette loading sequence.

Syringe Pump Dispense Calibration (32g needle dispenser)

Parameters: SA 50 accel ramp  ·  F14000 main dispense  ·  F10000 prime  ·  F6000 retract  ·  4-nozzle configuration

Calibration sweeps across five target volumes (40–190 µL total, 10–47.5 µL per nozzle). Each test uses a three-phase dispense sequence: prime, main dispense, and retract. An acceleration ramp of SA 50 was required at F14000 to prevent stepper skipping — at this feedrate the motor demands approximately 30,500 steps/sec, which exceeds reliable cold-start capability without ramping. SA 50 provides a minimal 50-step ramp sufficient to prevent stalling while keeping ramp length short enough to preserve accuracy at small volumes.

Test Prime Main Dispense Retract Retract Δ Total (4×) Per Nozzle
1 D1 E50 F10000
G4 P1000
D1 E120 F14000
G4 P500
A1 E120 F6000
G4 P100
0 µL ~190 µL 47.5 µL
2 D1 E40 F10000
G4 P1000
D1 E90 F14000
G4 P500
A1 E90 F6000
G4 P100
0 µL ~160 µL 40.0 µL
3 D1 E20 F10000
G4 P1000
D1 E80 F14000
G4 P500
A1 E80 F6000
G4 P100
0 µL ~85 µL 21.2 µL
4 D1 E20 F10000
G4 P1000
D1 E70 F14000
G4 P500
A1 E80 F6000
G4 P100
+10 µL ~50 µL 12.5 µL
5 D1 E20 F10000
G4 P1000
D1 E50 F14000
G4 P500
A1 E60 F6000
G4 P100
+10 µL ~40 µL 10.0 µL

Table 1 — Dispense calibration across five volume targets. Retract Δ = retract E − main dispense E. Positive Δ indicates active meniscus pullback.

At volumes below ~21 µL per nozzle, a retract offset of +10 µL is required to prevent satellite droplet formation at the nozzle orifice.

Observations

A
Acceleration ramp required at F14000

At F14000 the stepper demands approximately 30,500 steps/sec. Without ramping the motor stalls on cold start. SA 50 provides a minimal 50-step ramp — sufficient to prevent skipping at this feedrate while keeping ramp length short enough not to affect small volume accuracy. A longer ramp (SA 300+) would enable F16000+ but was not required for this calibration range.

P
Prime volume scales with dispense volume

Tests 1 and 2 use a larger prime (E50, E40) versus E20 for tests 3–5. At higher dispense volumes there is greater residual hydraulic pressure in the fluid path after the main dispense. The larger prime pre-pressurizes the system before the main dispense fires, ensuring the first drop delivers full volume rather than being under-filled due to pressure lag.

R
Retract offset appears below ~21 µL per nozzle

Tests 1–3 retract exactly the dispensed volume (Δ = 0). Tests 4 and 5 retract 10 µL more than dispensed. At smaller volumes the liquid column at the nozzle orifice has a higher surface-tension-to-volume ratio and tends to hang rather than break cleanly. The additional 10 µL of retract actively pulls the meniscus back into the nozzle, preventing satellite droplet formation and ensuring a clean break. The threshold appears to lie between 21.2 µL and 12.5 µL per nozzle.

S
500 ms pressure settle after main dispense

A 500 ms dwell (G4 P500) after the main dispense allows residual hydraulic pressure in the fluid path to equilibrate before retract fires. Without this dwell the retract competes with pressure still pushing liquid forward, resulting in inconsistent retract depth — particularly at higher dispense volumes where system pressure is greatest.

09 — Fabrication Process

7-Step PV Process Flow

Complete transparent PV fabrication on flexible ITO-PET substrates in a controlled N₂ environment — all steps executed on the Rister platform at ≤100°C:

1

UV-Ozone Cleaning

ITO-PET surface activation. 185 nm + 254 nm, 12–15 min. Target contact angle: <10°.

2

PEDOT:PSS Deposition

Hole transport layer. Printed onto activated ITO surface. Anneal 120°C / 20 min.

3

Perovskite Printing

FASnI₃ line-array deposition. N₂ atmosphere, 60°C heated pipette, 150 µm nozzle. Anneal 100°C / 10 min.

4

Electron Transport Layer

PCBM / SnO₂ deposition for charge extraction.

5

Electrode Formation

Silver nanowire or carbon-based top contact deposition.

6

Barrier Coating

UV-crosslinked encapsulant protecting perovskite from moisture and oxygen.

7

Encapsulation

Final lamination for mechanical and environmental protection.

10 — Strategy & Roadmap

Two-Horizon Strategy

Development is staged: validate the platform in a technically demanding real-world application first, then expand into adjacent markets from a position of demonstrated capability.

Horizon 1 — Active
Transparent Perovskite PV Film
FASnI₃ on ITO-PET targeting BIPV. 8–12% sunlight conversion at 55–65% light transmission. Validates platform in a demanding real-world deposition environment.
Horizon 2 — Future
Platform Expansion
Adjacent applications including flexible biosensors, battery electrode printing, and combinatorial materials R&D — contingent on Horizon 1 validation.

Development Roadmap

Q1–Q2 2026H1

UV-ozone activation validated; PEDOT:PSS deposition trials begin on ITO-PET substrates

Q3 2026H1

Lab partnership for perovskite characterization; sunlight conversion efficiency and transmittance measured

Q4 2026H1

First commercial pilot — Southern California BIPV retrofit partner; <$15/m² cost target validated

2027+H2

Platform expansion into adjacent deposition applications — contingent on Horizon 1 performance

11 — Next Steps

Immediate Priorities

01
UV-Ozone Substrate Activation
Establish ITO-PET hydrophilicity via 36W UVC (185 nm + 254 nm), 12–15 min at 200 mm standoff. Target contact angle: ~60–80° → <10°. Calibrate with Raspberry Pi contact angle imaging. Treat within 30–60 min of PEDOT:PSS deposition.
02
PEDOT:PSS Deposition Trials
First real-material deposition on activated ITO-PET substrates. Validate wetting, film uniformity, and adhesion before advancing to perovskite layer.
12 — Contact & Funding

Get Involved

Seeking lab partnerships, accelerator programs, and early-stage investors aligned with advanced manufacturing, thin-film materials, and California energy goals. Also open to conversations with research institutions interested in applying the platform to new materials applications.

Richard Rouse
HTS Resources, LLC · San Diego, California